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33 Advantages and Disadvantages Epoxies are useful at moderately high temperatures, up to about 150 C Because of their strength, they also provide mechanical support for components The disadvantages of epoxy coatings are their usually pungent odor and the possibility of skin irritation They are difficult to rework Some formulations of epoxies are chemically delicate and do not cure properly in the presence of inhibiting compounds Cure shrinkage is also of concern for fragile components; a softer buffer coating should be applied locally before the epoxy, particularly for assemblies that need to withstand wide swings in temperature 4124 Acrylics (Type AR) Acrylic coatings are applied 001 to 005 in thick and are often used in military and consumer electronics 41241 Chemistry Acrylic coatings are usually supplied as dissolved pre-polymerized acrylic chains.

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The acrylic chemistry does not cure by polymerization and cross-linking as the other coating materials do, but instead hardens gradually as the solvent evaporates Acrylics are also available in heat-curable and UV-cured formulations 41242 Properties Acrylics are easy to apply, and are the easiest coating to remove, since relatively mild solvents soften and dissolve the acrylic coating while leaving the epoxy encapsulated parts and PWB unharmed They can be cured quickly 41243 Advantages and Disadvantages The greatest strengths of acrylic coating are the ease of rework and the fast room temperature cureAcrylics provide good moisture resistance and fluoresce easily, aiding inspecting under UV lamps Since they are so easy to rework, acrylics are also susceptible to inadvertent chemical attack from solvent splash during hand cleaning of solder joints elsewhere in the assembly.

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The high emission of solvent inherent in the acrylic process makes them less environmentally friendly than other materials As the solvent evaporates, the coating shrinks and exerts stress on the components, so acrylics may not be suitable for all low-temperature applications 4125 Para-Xylylene (Type XY) Para-xylylene coatings are unique, since they are applied by vapor deposition (see Sec 4146) rather than as a liquid They are applied 0005 to 002 in thick Para-xylylene coatings are often used in biomedical devices due to the inert character of the coating..

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41.2.5.1 Chemistry. XY coating is supplied as a dimer, a polymer chain only two units long. During the vacuum deposition process, the dimer powder is gradually vaporized and is recondensed onto the CCA, polymerizing with the material already deposited. Typical application is .0005 to .002 in. thick. 41.2.5.2 Properties. XY coating is chemically inert and moisture-resistant. Very thin, uniform layers are possible, with no pinholes or voids. XY coating also has very high dielectric strength. Due to the nature of the deposition process, no volatiles are generated. 41.2.5.3 Advantages and Disadvantages. XY coating is the highest performing coating in many regards. It has the highest dielectric strength, and is the lightest weight, lowest outgassing, mostly chemically inert, and most moisture-resistant. It provides the most uniform coating over, under, and inside parts where liquid coatings cannot be applied. The coating process must be performed in batch mode, using specialized coating equipment. It may be impossible to mask adjustable components such as potentiometers adequately. Rework is difficult; since the thin coating cannot be peeled, a microabrasion process is usually required to remove the coating. Additional staking or adhesive bonding of parts is required, since the thin coating provides little mechanical support.

Most coating problems can be traced to improper preparation.The four preparation steps are:

Cleaning to remove flux, oils, and contaminants Masking to ensure coating is applied only where desired Preparing the surface or priming to promote adhesion of the coating Baking out to prevent moisture from being trapped under the coating

TABLE 5-4 32-KHZ OSCILLATOR START-UP TIMES AND CURRENT CONSUMPTION FOR VARIOUS CAPACITOR AND RESISTOR VALUES R1 C1 C2 START-UP TIME (SECONDS) I (DC) MA

Cleaning Thoroughly cleaning the CCA before conformal coating is the best way to ensure proper adhesion of the coating. The various cleaning chemistries and their effectiveness on different kinds of fluxes are treated in depth in the on, Fluxes and Cleaning. Besides removing flux, the cleaning process removes any contamination such as mold release agents on plastic part bodies, fingerprints, etc. No-clean fluxes reduce the need for waste water and waste solvent treatment. For boards that require conformal coating, the benefits of a no-clean system must be balanced with the risks of poor coating yields. A minor change in flux or coating chemistry could render the coating incompatible with the no-clean flux being used, causing delamination, cure inhibition, or other defects. In general, coating results are not as good with no-clean flux as with standard flux plus cleaning, yet in some cases may still be adequate to do the job.

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