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In April of 1956, a sharper decline in the bond market began Business then entered a traditional capital-goods boom that lasted until late 1957 The rise in consumer credit broke previous records The decline in the corporate bond price average from April 1954, to September 1957, amounted to some 22%; this was about as large as the largest previous cyclical decline, that of 1917 1920 Prime municipal prices declined about 21% The US 31 4s of 1978 1983 declined from a high of 1123 8 in 1954 to a low of 923 8 in 1957, a gross decline of nearly 18% The bill rate rose from 065% in 1954 to 359% in 1957 During 1957 the Treasury offered two small new long-term bond issues: 1957, Oct $07 billion 4s of 1969, fully taxable at 100 = 400% 1957, Dec 0.

Fig. 9-2 Scheme for utilization of a polymer substrate. After Mathur and Williams [1976] (by permission of Marcel Dekker, New York).

is treated with a low-molecular-weight reagent (and/or catalyst) R to yield the polymerP S bound product 0 and spent reagent R0 . Filtration separates the polymer-bound product. An appropriate reaction is carried out to cleave the desired product S0 from the polymer. The spent polymer support is ltered off, leaving the crude product S0 in the ltrate. The puri ed product S0 is obtained from the ltrate after solvent evaporation and appropriate puri cation.

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X to X bend FIGURE A-3: As seen in the Harmonic Window project, this variant of the 1 to X bend is useful for connecting many points together, but this time without there being a set single point common to all switches (point 1 in the 1 to X bend). Within the X to X bend, the 1 from the 1 to X bend simply becomes a variable. If all switches are turned off, no connection is made to the circuit. But if any of the switches are turned on, that switch then becomes the 1 in the traditional 1 to X bend: any further turning on of switches will connect their circuit points to the point of the switch (the variable 1 switch) turned on prior. This is a cool elaboration on the traditional 1 to X bend, often allowing a wider range of bent responses.

7 billion 37 8s of 1974, fully taxable at 100 = 387% In late 1957, the decline in the bond market was suddenly and sharply reversed A decline in the stock market was followed by signs that the business boom was faltering In November the Federal Reserve Banks signaled a reversal of policy by reducing the rediscount rate In two to four months the corporate bond price index rose 121 2%, Treasury 31 4s of 1978 1983 rose 12%, and the municipals index rose 13% in price The bill rate declined to 088% In early 1958 the Treasury took advantage of the better market by selling: 1958, Feb $17 billion 31 2s of 1990, fully taxable at 100 = 350% 1958, June 11 billion 31 4s of 1985, fully taxable at 1001 2 = 323%.

One of the most important applications of the polymer substrate technique is the solid-phase synthesis of polypeptides developed by Merri eld [Barany et al., 1988; Erickson and Merri eld, 1976; Kates and Abericio, 2000; Kent, 1988; Merri eld, 1978; 1985, 1988; Seward and Jakubke, 2002; Stewart, 1980]. Merri eld received the 1984 Nobel Prize in Chemistry for this achievement. Polypeptide synthesis is of interest for two reasons: (1) it is useful in con rming the structure of naturally occurring biological macromolecules and (2) it is a source of these substances as well as analogs that may show more desirable biological activity. Polypeptide synthesis involves the formation of an amide linkage between the amino and carboxyl groups of successive a-amino acid monomers. In reacting two different amino acids with each other, it is necessary to protect the amino group of one amino acid and protect the carboxyl of the other amino acid. This prevents self-reaction of each amino acid with itself and directs the synthesis in the desired cross-reaction route. There are two copolymerization routes and only one of these is the desired route. For example, alanylglycine (Eq. 9-72) and glycylalanine (Eq. 9-73) are possible from the cross-reaction of alanine and glycine. Synthesis of alanylglycine requires that the amine end of alanine and the carboxyl end of glycine be protected prior to reaction. Synthesis of glycylalanine requires that the amine and carboxyl ends of glycine and alanine, respectively, be protected.

9-73

9-72

Just as the business recession of 1957 1958 was sharp but brief, so the bond market rally of 1957 1958 was also sharp and very brief The price recovery was about as large as that of 1953 1954, but it was all accomplished in two to four months, as contrasted with the seventeen months recovery of 1948 1950 and the ten months recovery of 1953 1954 The first half of 1958 was characterized by unprecedented speculation in government bonds In May and June of 1958, early signs of business recovery caught bond speculators by surprise, and the brief, intense bond market boom collapsed The prospect of a large Treasury deficit in a period of recovery induced expectations of inflation at home and fear.

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